Compound Information 

Name: trifluoromethane
Formula: CHF3
Molar Mass: 70.0142096
Additional Names: freon F-23
methane, trifluoro-
arcton 1
carbon trifluoride
FC 23
fluoryl
freon 23
genetron 23
HFC 23
methyl trifluoride
R-23
fluoroform
Image of trifluoromethane

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Property Availability 

For this compound, WTT contains critically evaluated recommendations for:
(Please note that if more than 50 points are used for regression, only the 50 most-constraining points are reported)

  • Triple point temperature (Crystal 1, Liquid, and Gas)
    5 experimental data points
    • Normal boiling temperature (Liquid and Gas)
      • Critical temperature (Liquid and Gas)
        14 experimental data points
        • Critical pressure (Liquid and Gas)
          7 experimental data points
          • Boiling temperature (Liquid in equilibrium with Gas) as a function of Pressure
            Pressure from 0.058041 kPa to 4832 kPa
            • Phase boundary pressure
              • Phase boundary pressure (Liquid in equilibrium with Gas) as a function of Temperature
                Temperature from 118.02 K to 299.293 K
                50 experimental data points
              • Phase boundary pressure (Crystal 1 in equilibrium with Liquid) as a function of Temperature
                Temperature from 117.974 K to 140.614 K
                17 experimental data points
            • Critical density (Liquid and Gas)
              9 experimental data points
              • Density
                • Density (Liquid in equilibrium with Gas) as a function of Temperature
                  Temperature from 118.02 K to 299.293 K
                  50 experimental data points
                • Density (Gas in equilibrium with Liquid) as a function of Temperature
                  Temperature from 118.02 K to 299.293 K
                  50 experimental data points
                • Density (Liquid) as a function of Temperature and Pressure
                  Temperature from 118.02 K to 299.293 K
                  Pressure from 0.1 kPa to 120000 kPa
                  50 experimental data points
                • Density (Gas) as a function of Temperature and Pressure
                  Temperature from 118.02 K to 475 K
                  Pressure from 0.1 kPa to 4832 kPa
                  49 experimental data points
              • Isobaric coefficient of expansion
                • Isobaric coefficient of expansion (Liquid) as a function of Temperature and Pressure
                  Temperature from 118.02 K to 299.293 K
                  Pressure from 0.1 kPa to 120000 kPa
                • Isobaric coefficient of expansion (Gas) as a function of Temperature and Pressure
                  Temperature from 118.02 K to 475 K
                  Pressure from 0.1 kPa to 4832 kPa
              • Isothermal compressibility
                • Isothermal compressibility (Liquid) as a function of Temperature and Pressure
                  Temperature from 118.02 K to 299.293 K
                  Pressure from 0.1 kPa to 120000 kPa
                • Isothermal compressibility (Gas) as a function of Temperature and Pressure
                  Temperature from 118.02 K to 475 K
                  Pressure from 0.1 kPa to 4832 kPa
              • Thermal pressure coefficient
                • Thermal pressure coefficient (Liquid) as a function of Temperature and Pressure
                  Temperature from 118.02 K to 299.293 K
                  Pressure from 0.1 kPa to 120000 kPa
                • Thermal pressure coefficient (Gas) as a function of Temperature and Pressure
                  Temperature from 118.02 K to 475 K
                  Pressure from 0.1 kPa to 4832 kPa
              • 2nd virial coefficient (Gas) as a function of Temperature
                Temperature from 118.02 K to 475 K
                44 experimental data points
                • 3rd virial coefficient (Gas) as a function of Temperature
                  Temperature from 118.02 K to 475 K
                  34 experimental data points
                  • Enthalpy of phase transition (Crystal 1 to Liquid in equilibrium with Gas)
                    2 experimental data points
                    • Enthalpy of vaporization or sublimation (Liquid to Gas) as a function of Temperature
                      Temperature from 118.02 K to 299.293 K
                      50 experimental data points
                      • Heat capacity at saturation pressure
                        • Heat capacity at saturation pressure (Liquid in equilibrium with Gas) as a function of Temperature
                          Temperature from 118.02 K to 299.1 K
                          50 experimental data points
                        • Heat capacity at saturation pressure (Crystal 1 in equilibrium with Gas) as a function of Temperature
                          Temperature from 0.0001 K to 117.973 K
                          48 experimental data points
                      • Heat capacity at constant pressure
                        • Heat capacity at constant pressure (Liquid) as a function of Temperature and Pressure
                          Temperature from 118.02 K to 299.293 K
                          Pressure from 0.1 kPa to 120000 kPa
                          50 experimental data points
                        • Heat capacity at constant pressure (Ideal Gas) as a function of Temperature
                          Temperature from 50 K to 3000 K
                          50 experimental data points
                        • Heat capacity at constant pressure (Gas) as a function of Temperature and Pressure
                          Temperature from 118.02 K to 475 K
                          Pressure from 0.1 kPa to 4832 kPa
                          50 experimental data points
                      • Enthalpy
                        • Enthalpy (Crystal 1 in equilibrium with Gas) as a function of Temperature
                          Temperature from 0.0001 K to 117.973 K
                        • Enthalpy (Liquid in equilibrium with Gas) as a function of Temperature
                          Temperature from 117.974 K to 286.147 K
                        • Enthalpy (Ideal Gas) as a function of Temperature
                          Temperature from 50 K to 3000 K
                      • Entropy
                        • Entropy (Crystal 1 in equilibrium with Gas) as a function of Temperature
                          Temperature from 0.0001 K to 117.973 K
                          16 experimental data points
                        • Entropy (Liquid in equilibrium with Gas) as a function of Temperature
                          Temperature from 118.02 K to 299.293 K
                          10 experimental data points
                        • Entropy (Ideal Gas) as a function of Temperature and Pressure
                          Temperature from 50 K to 3000 K
                      • Adiabatic compressibility
                        • Adiabatic compressibility (Liquid) as a function of Temperature and Pressure
                          Temperature from 118.02 K to 299.293 K
                          Pressure from 0.1 kPa to 120000 kPa
                        • Adiabatic compressibility (Gas) as a function of Temperature and Pressure
                          Temperature from 118.02 K to 475 K
                          Pressure from 0.1 kPa to 4832 kPa
                      • Pressure coefficient of enthalpy
                        • Pressure coefficient of enthalpy (Gas) as a function of Temperature and Pressure
                          Temperature from 118.02 K to 475 K
                          Pressure from 0.1 kPa to 4832 kPa
                          50 experimental data points
                        • Pressure coefficient of enthalpy (Liquid) as a function of Temperature and Pressure
                          Temperature from 118.02 K to 299.293 K
                          Pressure from 0.1 kPa to 120000 kPa
                      • Joule-Thomson coefficient (Gas) as a function of Temperature and Pressure
                        Temperature from 118.02 K to 475 K
                        Pressure from 0.1 kPa to 4832 kPa
                        • Speed of sound
                          • Speed of sound (Liquid) as a function of Temperature and Pressure
                            Temperature from 118.02 K to 299.293 K
                            Pressure from 0.1 kPa to 120000 kPa
                            50 experimental data points
                          • Speed of sound (Gas) as a function of Temperature and Pressure
                            Temperature from 118.02 K to 475 K
                            Pressure from 0.1 kPa to 4832 kPa
                            50 experimental data points
                          • Speed of sound (Liquid in equilibrium with Gas) as a function of Temperature
                            Temperature from 118.02 K to 299.293 K
                          • Speed of sound (Gas in equilibrium with Liquid) as a function of Temperature
                            Temperature from 118.02 K to 299.293 K
                        • Surface tension (Liquid in equilibrium with Gas) as a function of Temperature
                          Temperature from 118.02 K to 299.293 K
                          36 experimental data points
                          • Viscosity
                            • Viscosity (Gas) as a function of Temperature and Pressure
                              Temperature from 118.02 K to 475 K
                              Pressure from 0.1 kPa to 4832 kPa
                              50 experimental data points
                            • Viscosity (Liquid) as a function of Temperature and Pressure
                              Temperature from 118.02 K to 299.293 K
                              Pressure from 0.1 kPa to 120000 kPa
                              220 experimental data points
                            • Viscosity (Liquid in equilibrium with Gas) as a function of Temperature
                              Temperature from 118.02 K to 299.1 K
                              16 experimental data points
                          • Thermal conductivity
                            • Thermal conductivity (Liquid in equilibrium with Gas) as a function of Temperature
                              Temperature from 118.02 K to 299.1 K
                              50 experimental data points
                            • Thermal conductivity (Gas) as a function of Temperature and Pressure
                              Temperature from 118.02 K to 475 K
                              Pressure from 0.1 kPa to 4832 kPa
                              46 experimental data points
                            • Thermal conductivity (Liquid) as a function of Temperature and Pressure
                              Temperature from 118.02 K to 299.293 K
                              Pressure from 0.1 kPa to 120000 kPa
                              50 experimental data points

                          About WTT 

                          NIST/TRC Web Thermo Tables (WTT)
                          NIST Standard Reference Subscription Database 3 - Professional Edition
                          Version 2-2012-1-Pro

                          This web application provides access to a collection of critically evaluated thermodynamic property data for pure compounds with a primary focus on organics. These data were generated through dynamic data analysis, as implemented in the NIST ThermoData Engine software package [1, 2, 3, 4, 5, 6]. Some critically evaluated data from the historical TRC Thermodynamic Tables archive [7, 8] are included, also. As of May 2012, the Professional Edition contains information on 28432 compounds and total of 531486 evaluated data points. The properties covered by both versions (32 total) are described in Properties and Implemented Models.

                          Developed by Kenneth Kroenlein, Chris D. Muzny, Andrei F. Kazakov, Vladimir Diky, Robert D. Chirico, Joseph W. Magee, Ilmutdin Abdulagatov and Michael Frenkel.

                          Thermodynamics Research Center (TRC)
                          Thermophysical Properties Division
                          National Institute of Standards and Technology
                          Boulder CO 80305-3337

                          Questions and comments should be addressed to Dr. Michael Frenkel .

                          DISCLAIMER: The National Institute of Standards and Technology (NIST) uses its best efforts to deliver a high-quality copy of the database and to verify that the methods and data contained therein have been selected on the basis of sound scientific judgement. However, NIST makes no warranties to that effect, and NIST shall not be liable for any damage that may result from errors or omissions in the program and database.

                          Distributed by:
                          Standard Reference Data Program
                          National Institute of Standards and Technology
                          Gaithersburg MD 20899

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